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HPLC Determination of ethoxylated alcohol surfactants in wastewater

Identifieur interne : 001481 ( Main/Exploration ); précédent : 001480; suivant : 001482

HPLC Determination of ethoxylated alcohol surfactants in wastewater

Auteurs : T. M. Schmitt [États-Unis] ; M. C. Allen [États-Unis] ; D. K. Brain [États-Unis] ; K. F. Guin [États-Unis] ; D. E. Lemmel [États-Unis] ; Q. W. Osburn [États-Unis]

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RBID : ISTEX:59DF995D9E9A0A7B74CAEC44B9CC713B8E305543

Abstract

Abstract: High performance liquid chromatography (HPLC) may be used for analysis of municipal wasterwater containing ethoxylated alcohol surfactants. After cleanup of the sample by XAD-2 resin, liquid-liquid extraction, ion exchange and cobalt thiocyanate extraction, the surfactant is derivatized with phenyl isocyanate to permit UV detection and analyzed by both normal phase and reversedphase HPLC. The alkyl chain length distribution is determined using reversed-phase HPLC, while the ethoxy chain length is determined by normal phase HPLC. The limit of quantification is 0.1 ppm.

Url:
DOI: 10.1007/BF02540636


Affiliations:


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<div type="abstract" xml:lang="en">Abstract: High performance liquid chromatography (HPLC) may be used for analysis of municipal wasterwater containing ethoxylated alcohol surfactants. After cleanup of the sample by XAD-2 resin, liquid-liquid extraction, ion exchange and cobalt thiocyanate extraction, the surfactant is derivatized with phenyl isocyanate to permit UV detection and analyzed by both normal phase and reversedphase HPLC. The alkyl chain length distribution is determined using reversed-phase HPLC, while the ethoxy chain length is determined by normal phase HPLC. The limit of quantification is 0.1 ppm.</div>
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